VCAA Chemistry How can the rate and yield of chemical reactions be optimised?

5 sample questions with marking guides and sample answers

Q17
2024
QCAA
Paper 1
1 mark
Q17
1 mark

Identify the product produced at the cathode when a concentrated aqueous solution of NaCl undergoes electrolysis.

A

Cl2_2(g)

B

Na(l)

C

O2_2(g)

D

H2_2(g)

Q1
2023
QCAA
Paper 1
1 mark
Q1
1 mark

In a chemical equation at equilibrium, a reversible arrow (\rightleftharpoons) symbolises that

A

the forward reaction has stopped but can be reversed.

B

the moles of reactants and products present are equal.

C

half of the reactants have been converted into products.

D

the concentration of reactants and products remains constant.

Q21
2024
QCAA
Paper 1
3 marks
Q21

Reactants A and B are placed in a 1.00 L container and react to form product C. The reaction then reaches equilibrium.

A(g)+B(g)C(g)(Kc=9.9×102)\text{A(g)} + \text{B(g)} \rightleftharpoons \text{C(g)} \quad (K_c = 9.9 \times 10^2)

Q21a
1 mark

Explain why a reversible arrow (\rightleftharpoons) is used to symbolise this reaction.

Q21b
2 marks

Deduce whether the equilibrium for the reaction lies towards the reactants or products. Explain your reasoning.

Q25
2023
QCAA
Paper 1
7 marks
Q25

During the contact process for manufacturing sulfuric acid, sulfur dioxide (SO2\text{SO}_2) and oxygen (O2\text{O}_2) are passed over a vanadium oxide catalyst to produce sulfur trioxide (SO3\text{SO}_3). In the process, the vanadium oxide undergoes the following reactions.

Reaction 1: SO2(g)+V2O5(s)SO3(g)+V2O4(s)\text{SO}_2\text{(g)} + \text{V}_2\text{O}_5\text{(s)} \rightarrow \text{SO}_3\text{(g)} + \text{V}_2\text{O}_4\text{(s)}
Reaction 2: 2V2O4(s)+O2(g)2V2O5(s)2\text{V}_2\text{O}_4\text{(s)} + \text{O}_2\text{(g)} \rightarrow 2\text{V}_2\text{O}_5\text{(s)}
Overall reaction: 2SO2(g)+O2(g)V2O5(s)2SO3(g)2\text{SO}_2\text{(g)} + \text{O}_2\text{(g)} \xrightarrow{\text{V}_2\text{O}_5\text{(s)}} 2\text{SO}_3\text{(g)}

Q25a
1 mark

Determine the oxidation state of vanadium in V2O4(s)\text{V}_2\text{O}_4\text{(s)}.

Q25b
2 marks

Determine if vanadium in V2O5(s)\text{V}_2\text{O}_5\text{(s)} in reaction 1 is acting as an oxidising or reducing agent. Explain your reasoning.

Q25c
4 marks

Use the reactions provided to explain why V2O5(s)\text{V}_2\text{O}_5\text{(s)} is a catalyst for the overall reaction.

Q7
2023
QCAA
Paper 2
4 marks
Q7

When heated in a sealed container, solid mercury(II) oxide (HgO) decomposed to form metallic mercury (Hg) and oxygen gas (O2_2).

2HgO(s)2Hg(l)+O2(g)2\text{HgO(s)} \rightleftharpoons 2\text{Hg(l)} + \text{O}_2\text{(g)}
Orange \quad Silver \quad Colourless

Q7a
1 mark

Identify whether the reaction occurs in an open or closed system.

Q7b
3 marks

Explain why the colour of the system does not change once equilibrium is established.

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