QCAA Chemistry Chemical equilibrium systems

5 sample questions with marking guides and sample answers

Q1
2024
QCAA
Paper 1
1 mark
Q1
1 mark

The question refer sto hydrated copper sulfate and its decomposition when heated.

Hydrated copper sulfate (CuSO4H2OCuSO_4\cdot H_2O) decomposes to form copper sulfate (CuSO4_4) and water when heated.

heat+CuSO4H2O(s)CuSO4(s)+H2O(g)\text{heat} + \text{CuSO}_4\cdot\text{H}_2\text{O(s)} \rightleftharpoons \text{CuSO}_4\text{(s)} + \text{H}_2\text{O(g)}

Which of the following is exchanged with the surrounding environment when CuSO4_4xH2_2O(s) is heated in a closed system to establish dynamic equilibrium?

A

heat

B

H2_2O(g)

C

CuSO4_4(s) + H2_2O(g)

D

heat + CuSO4_4xH2_2O(s)

Q1
2021
QCAA
Paper 1
1 mark
Q1
1 mark

Melting is a

A

physical change that is reversible.

B

chemical change that is reversible.

C

physical change that is irreversible.

D

chemical change that is irreversible.

Q21
2024
QCAA
Paper 1
3 marks
Q21

Reactants A and B are placed in a 1.00 L container and react to form product C. The reaction then reaches equilibrium.

A(g)+B(g)C(g)(Kc=9.9×102)\text{A(g)} + \text{B(g)} \rightleftharpoons \text{C(g)} \quad (K_c = 9.9 \times 10^2)

Q21a
1 mark

Explain why a reversible arrow (\rightleftharpoons) is used to symbolise this reaction.

Q21b
2 marks

Deduce whether the equilibrium for the reaction lies towards the reactants or products. Explain your reasoning.

Q3
2024
QCAA
Paper 2
9 marks
Q3

The concentration, pH and dissociation constant (KaK_a) of aqueous solutions of ethanoic acid and two unknown monoprotic acids, I and II, are shown.

AcidConcentration (M)pHKaK_a
CH3_3COOH(aq)0.2 1.8×1051.8 \times 10^{-5}
I0.21.96.6×1046.6 \times 10^{-4}
II0.11.11.3×1061.3 \times 10^6
Q3a
3 marks

Compare the relative strength of an aqueous solution of acid I and CH3_3COOH(aq).

Q3b
3 marks

Determine whether an aqueous solution of acid I or acid II would have a higher electrical conductivity. Explain your reasoning.

Q3c
3 marks

Calculate the pH of 0.2 M CH3_3COOH(aq). Show your working.

Q7
2023
QCAA
Paper 2
4 marks
Q7

When heated in a sealed container, solid mercury(II) oxide (HgO) decomposed to form metallic mercury (Hg) and oxygen gas (O2_2).

2HgO(s)2Hg(l)+O2(g)2\text{HgO(s)} \rightleftharpoons 2\text{Hg(l)} + \text{O}_2\text{(g)}
Orange \quad Silver \quad Colourless

Q7a
1 mark

Identify whether the reaction occurs in an open or closed system.

Q7b
3 marks

Explain why the colour of the system does not change once equilibrium is established.

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